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91.
92.
本文对Hg的577 nm、579 nm谱线的塞曼效应进行了理论分析和实验验证,通过对F-P标准具分辨率的讨论.证明实验现象与理论分析是一致的.定量计算了分裂谱线的波数差. 相似文献
93.
Jürgen Geiser 《Numerical Methods for Partial Differential Equations》2011,27(5):1026-1054
In this article, we consider iterative operator‐splitting methods for nonlinear differential equations with bounded and unbounded operators. The main feature of the proposed idea is the embedding of Newton's method for solving the split parts of the nonlinear equation at each step. The convergence properties of such a mixed method are studied and demonstrated. We confirm with numerical applications the effectiveness of the proposed scheme in comparison with the standard operator‐splitting methods by providing improved results and convergence rates. We apply our results to deposition processes. © 2010 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 27: 1026–1054, 2011 相似文献
94.
本文利用Fourier分解方法研究Boussinesq方程组Cauchy问题弱解的L2衰减下界估计. 相似文献
95.
In this paper, we consider the solution of linear systems of saddle point type by a preconditioned numerical method. We first transform the original linear system into two sub-systems with small size by a preconditioning strategy, then employ the conjugate gradient (CG) method to solve the linear system with a SPD coefficient matrix, and a splitting iteration method to solve the other sub-system, respectively. Numerical experiments show that the new method can achieve faster convergence than several effective preconditioners published in the recent literature in terms of total runtime and iteration steps. 相似文献
96.
Let K be a knot in a sphere S3. We denote by t(K) the tunnel number of K. For two knots K1 and K2, we denote by K1?K2 the connected sum of K1 and K2. In this paper, we will prove that if one of K1 and K2 has high distance while the other has distance at least 3 then t(K1?K2)=t(K1)+t(K2)+1. 相似文献
97.
In this paper, we show the following result: Let K
i
be a knot in a closed orientable 3-manifold M
i
such that (M
i
,K
i
) is not homeomorphic to (S
2 ×S
1, x
0 ×S
1), i = 1, 2. Suppose that the Euler Characteristic of any meridional essential surface in each knot complement E(K
i
) is less than the difference of one and twice of the tunnel number of K
i
. Then the tunnel number of their connected sum will not go down. If in addition that the distance of any minimal Heegaard
splitting of each knot complement is strictly more than 2, then the tunnel number of their connected sum is super additive. 相似文献
98.
Haojie Zhang Dirk J. Hagen Xiaopeng Li Andreas Graff Frank Heyroth Bodo Fuhrmann Ilya Kostanovskiy Stefan L. Schweizer Francesco Caddeo A. Wouter Maijenburg Stuart Parkin Ralf B. Wehrspohn 《Angewandte Chemie (International ed. in English)》2020,59(39):17172-17176
Transition‐metal phosphides (TMP) prepared by atomic layer deposition (ALD) are reported for the first time. Ultrathin Co‐P films were deposited by using PH3 plasma as the phosphorus source and an extra H2 plasma step to remove excess P in the growing films. The optimized ALD process proceeded by self‐limited layer‐by‐layer growth, and the deposited Co‐P films were highly pure and smooth. The Co‐P films deposited via ALD exhibited better electrochemical and photoelectrochemical hydrogen evolution reaction (HER) activities than similar Co‐P films prepared by the traditional post‐phosphorization method. Moreover, the deposition of ultrathin Co‐P films on periodic trenches was demonstrated, which highlights the broad and promising potential application of this ALD process for a conformal coating of TMP films on complex three‐dimensional (3D) architectures. 相似文献
99.
Jin Su Takashi Hisatomi Tsutomu Minegishi Kazunari Domen 《Angewandte Chemie (International ed. in English)》2020,59(33):13800-13806
Most CdTe photoanodes and photocathodes show positive and negative photocurrent onset potentials for water oxidation and reduction, respectively, and are thus unable to drive photoelectrochemical (PEC) water splitting without external applied biases. Herein, the activity of a CdTe photoanode having an internal p‐n junction during PEC water oxidation was enhanced by applying a CdCl2 annealing treatment together with surface modifications. The resulting CdTe photoanode generated photocurrents of 1.8 and 5.4 mA cm?2 at 0.6 and 1.2 VRHE, respectively, with a photoanodic current onset potential of 0.22 VRHE under simulated sunlight (AM 1.5G). The CdCl2 annealing increased the grain sizes and lowered the density of grain boundaries, allowing more efficient charge separation. Consequently, a two‐electrode tandem PEC cell comprising a CdTe‐based photoanode and photocathode split water without any external bias at a solar‐to‐hydrogen conversion efficiency of 0.51 % at the beginning of the reaction. 相似文献
100.
Shijia Feng Tuo Wang Bin Liu Congling Hu Lulu Li Zhi‐Jian Zhao Jinlong Gong 《Angewandte Chemie (International ed. in English)》2020,59(5):2044-2048
A facile photoetching approach is described that alleviates the negative effects from bulk defects by confining the oxygen vacancy (Ovac) at the surface of BiVO4 photoanode, by 10‐minute photoetching. This strategy could induce enriched Ovac at the surface of BiVO4, which avoids the formation of excessive bulk defects. A mechanism is proposed to explain the enhanced charge separation at the BiVO4 /electrolyte interface, which is supported by density functional theory (DFT) calculations. The optimized BiVO4 with enriched surface Ovac presents the highest photocurrent among undoped BiVO4 photoanodes. Upon loading FeOOH/NiOOH cocatalysts, photoetched BiVO4 photoanode reaches a considerable water oxidation photocurrent of 3.0 mA cm?2 at 0.6 V vs. reversible hydrogen electrode. An unbiased solar‐to‐hydrogen conversion efficiency of 3.5 % is realized by this BiVO4 photoanode and a Si photocathode under 1 sun illumination. 相似文献